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The role of selective contacts and built-in field for charge separation and transport in photoelectrochemical devices M. Schleuning, I. Y. Ahmet, R. van de Krol and M. M. May, Sustainable Energy Fuels, 2022, 6, 3701 DOI: 10.1039/D2SE00562J This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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Prof. Dr. Roel van de Krol TU Berlin Helmholtz-Zentrum Berlin für Materialien und Energie GmbH Institute for Solar Fuels Hahn-Meitner-Platz 1 14109 Berlin
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A soft chemical approach, hydrothermal method, was used to introduce sulfur atoms into bismuth vanadate (BiVO4), prolonging the light absorption edge of BiVO4 from 530 nm to nearly 650 nm, while the.
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In situ observation of pH change during water splitting in neutral pH conditions: impact of natural convection driven by buoyancy effects . K. Obata, R. van de Krol, M. Schwarze, R. Schomäcker and F. F. Abdi, Energy Environ.Sci., 2020, 13, 5104 DOI: 10.1039/D0EE01760D This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
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Solar energy-driven overall water splitting (OWS) is an attractive way for generating clean and renewable green hydrogen. One key challenge is the construction of OWS systems with high solar energy conversion efficiencies, in which how to manipulate photoexcited charge carriers to efficiently participate in the reaction is the top priority.
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The direct conversion of solar energy into hydrogen represents an attractive but challenging alternative for photo-voltaic solar cells. Several metal oxide semiconductors are able to split water into hydrogen and oxygen upon illumination, but the efficiencies are still (too) low. The operating principles of photo-electrochemical devices for water splitting, their main bottlenecks, and the.
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Dennis Friedrich. Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, Berlin, 14109 Germany
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Dense, homogeneous CuBi2O4 thin films are prepared, for the first time, by spray pyrolysis. Major challenges related to the chemical stability of the precursor solution and spreading behavior of the sprayed droplets are revealed and addressed. Triethyl orthoformate (TEOF) is added as a water scavenger to avo
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Note that the aqueous mixed solution of 1.5 M K 2 HPO 4 +KH 2 PO 4 was used as the near-neutral electrolyte (buffered near-neutral pH solution) to avoid the deviation of pH at the electrode surface from the bulk. 61 All electrolytes were prepared in 18.2 MΩ cm de-ionized water and the pH values of the electrolytes were measured using a pH-meter (FiveEasy Kit, METTLER TOLEDO).
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Gerrit Krol 19342013 De Groene Amsterdammer
Photoelectrochemical Hydrogen Production is a one-stop resource for scientists, students and R&D practitioners starting in this field, providing both the theoretical background as well as useful practical information on photoelectrochemical measurement techniques. Experts in the field benefit from the chapters on current state-of-the-art.
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Reference Abdi, Chemseddine, Berglund and van de Krol 42 The field also needs to recognize when well-studied materials such as TiO 2, α-Fe 2 O 3, and even BiVO 4 (which is certainly useful for scale-up studies but is theoretically limited to 9% STH efficiency by its 2.4 eV band gap) are not going to solve the problem and refocus their resources and knowledge on the search and optimization of.
